煤焦油加氢制燃料油的试验研究

实验室研究利用煤焦油研制汽柴油替代品燃料油.以高温煤焦油为原料,选择加氢保护剂、脱金属剂及加氢精制催化剂,采用加氢工艺,脱除煤焦油中硫、氮、氧和金属等有害杂质,使煤焦油中烯烃饱和,从而改善煤焦油质量,制得合格的汽油、柴油替代品燃料油.     

热-力耦合作用对建筑结构火灾安全的影响

结构火灾安全可以避免建筑物在火灾中坍塌.火灾热环境影响建筑结构的响应,传统的标准火灾环境有一定的局限性,不能完全适用于若干真实火灾场景.因此有必要开展真实火灾环境下建筑结构的热-力响应特性研究,发展有效的工程工具来设计经济安全的结构.近来,性能化的结构火灾安全设计评估方法和相应技术发展迅速,该文给出一种综合考虑热-力耦合作用的结构火灾安全设计评估方法及相应流程.首先通过建筑和燃料特性来预测可能的火灾热环境特性,然后再分析构件和结构的热响应和力学响应特性来判定结构是否会失效,以及可以降低热和力影响的预防失效措施.该文通过案例分析将该方法应用于某中庭钢结构屋顶的防火保护,得到经济合理的防火涂层设计,满足有关防火规范的安全等价要求.     

城市富营养化水域的生物治理和凤眼莲抑制藻类生长的机理

应用凤眼莲生态系统治理了上海市区一条富营养化河浜,使水质改善,由于藻类生长受到控制而水变澄清。凤眼莲抑制藻类生长的作用机制除了对光和矿质营养的竞争外,主要是由于凤眼莲根系向水体分泌化合物,能伤害和清除藻类(剋制作用Allelopaihic effect)。根圈栖生的一种软体动物——水蜗牛,以藻类为食,也是凤眼莲生态系统清除藻类的一个因素。     

全球变暖 夏季变凉

气候变化历来为人类所重视。近几十年来频繁而强烈的气候异常 ,已使人们认识到超极限地使用自然资源和气候资源、无所顾忌地排放各种污染物给人类带来的灾难。文章在总结、分析前人对未来气候变化的各种理论的基础上 ,根据影响气候的各因子及反馈关系的研究 ,提出未来世界气候变化的总体趋势是 :全球变暖 ,夏季变凉 ,气候异常将更加剧烈和频繁     

The acute lethality and endocrine effect of 1,2,3,7,8-PeCDD in juvenile goldfish （ Carassius auratus ） in vivo

1,2,3,7,8-PeCDD was administrated to juvenile goldfish （Carassius auratus） by peritoneal injections to explore the acute lethality and endocrine effects of 1,2,3,7,8-PeCDD in vivo. The value of acute median lethal dosage （LD50） of 1,2,3,7,8-PeCDD was determined in acute lethality tests. The endocrine effect of 1,2,3,7,8-PeCDD, whose exposed concentrations were determined based on the LD50 （1.84 mg/kg）, was studied by measuring the plasma vitellogenin （Vtg） content in juvenile male goldfish with enzyme-linked immunosorbent assays （ELISA）. Due to its significant induction of the plasma Vtg after one week＇s exposure in vivo in the 1/2 LD50 and LD30 groups, 1,2,3,7,8-PeCDD might be one of the important contributors to the estrogenic effect of PCDDs in the environment. The values of 1/2 LD50 and LD30 were within the range of the effective dosages of 1,2,3,7,8-PeCDD, indicating that there was a certain relationship between the estrogenic effective dosages and the LD50.     

粉煤灰的粉体特性及其对减水效应的影响

通过对粉煤灰颗粒形貌、平均粒径、粒度分布等粉体特性参量的测定和计算分析 ,发现粉煤灰的减水效应主要来自圆球形玻璃微珠的滚珠轴承润滑作用或对水泥絮凝结构的分散作用。过细的粉煤灰大掺量取代水泥后有可能会降低其减水效应     

Estimation of probabilities and likely consequences of a chain of accidents (domino effect) in Manali Industrial Complex

Chains of accidents (the domino effect) have been occurring with ever increasing frequency in chemical process industries. This is reflected in several accidents ‘J Loss Prevent Process Ind 12 (1999a) 361’; the world's worst industrial accident of the 1990s — the Vishakhpatnam disaster — also involved the domino effect ‘J Loss Prevent Process Ind 12 (1999a) 361; and Process Safety Prog 18 (1999b) 135’. Such chains of accidents have a greater propensity to cause damage than stand-alone accidents ‘Process Safety Prog 17(2) (1998a) 107; and J Loss Prevent Process Ind 12 (1999a) 361’.In order to assess the likelihood of occurrence of the domino effect and its damage potential, use of deterministic models in conjunction with probabilistic analysis is required. Recently we have proposed a systematic methodology called ‘domino effect analysis’ (DEA). A computer-automated tool, DOMIFFECT, has also been developed by us based on DEA ‘Process Safety Prog 17(2) (1998a) 107; Environment Model Software 13 (1998b) 163; and Risk assessment in chemical process industries: advanced techniques. Discovery Publishing House (1998c)’.This paper illustrates the application of DEA and DOMIFFECT to an industrial complex comprising 16 different industries. Out of 12 credible accident scenarios envisaged in three different industries — namely Madras Refineries Limited (MRL), UB Petrochemicals (UBP) and Indian Organic Chemicals Limited (IOCL), eight scenarios are likely to cause the domino effect. A further detailed analysis reveals that accidents in the storage of liquified petroleum gas and propylene and in the reflux drum units of MRL may cause domino effects. Similarly, propylene storage of UBP and monoethylene glycol storage of IOCL are also likely to cause domino effects. The impact of various chains of accidents has been forecast which reveals that in several cases the accidents may be catastrophic, harming the entire industrial complex of 16 industries. The study leads to the identification of ‘hot spots’ — units that pose the greatest risk — in turn forewarning the industries concerned and enabling them to prioritize and augment accident-prevention steps.     

Electrically enhanced photodegradation of an azodye(Acid Orange II) using a Pt/TiO_2 film electrode irradiating with an UV lamp

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无锡市城镇化进程中土地利用变化及其环境效应

20世纪90年代,城市用地扩展是我国区域土地利用演化的主导过程,城市土地利用所引起的地表景观格局的变化又是引起地表各种地理过程变化的主要原因。基于Landsat TM图像解译的土地利用的动态图斑,分析了20年代90年代无锡市土地利用的变化态势。研究表明,土地利用变化主要体现为耕地向林地、水域、建设用地的转移．林地向耕地、建设用地的转移,以及草地、水域向建设用地的转移;20世纪90年代中后期,国家颁布的一系列基本农田保护和“退耕还林还草”的政策法规,在一定程度上限制了大量耕地被建设占用的趋势。土地利用快速变化也导致明显环境效应．主要表现为水环境的恶化和现代“城市病”等方面。因此,加强土地规划管理、合理利用土地资源、重视能源开发与基础设施建设,应成为今后区域土地资源开发、利用与保护的重点与方向。